Vacancy coalescence during oxidation of iron nanoparticles.

نویسندگان

  • Andreu Cabot
  • Victor F Puntes
  • Elena Shevchenko
  • Yadong Yin
  • Lluís Balcells
  • Matthew A Marcus
  • Steven M Hughes
  • A Paul Alivisatos
چکیده

Andreu Cabot,† Victor F. Puntes,‡ Elena Shevchenko,§ Yadong Yin,§,| Lluı́s Balcells,⊥ Matthew A. Marcus,¶ Steven M. Hughes,# and A. Paul Alivisatos*,†,§,# Materials Sciences DiVision, Molecular Foundry, and AdVanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California 94720, Institut Català d’ Estudis i Recerca AVançat and Institut Catalá de Nanotecnologia, Bellaterra 08193, Barcelona, Spain, Institut de Ciència de Materials de Barcelona, (ICMAB-CSIC), Campus UAB, Bellaterra 08193, Spain, and Department of Chemistry, UniVersity of California at Berkeley, Berkeley, California 94720

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

In-Situ TEM visualization of vacancy injection and chemical partition during oxidation of Ni-Cr nanoparticles

Oxidation of alloy often involves chemical partition and injection of vacancies. Chemical partition is the consequence of selective oxidation, while injection of vacancies is associated with the differences of diffusivity of cations and anions. It is far from clear as how the injected vacancies behave during oxidation of metal. Using in-situ transmission electron microscopy, we captured unprece...

متن کامل

Monodispersed bimetallic PdAg nanoparticles with twinned structures: Formation and enhancement for the methanol oxidation

Monodispersed bimetallic PdAg nanoparticles can be fabricated through the emulsion-assisted ethylene glycol (EG) ternary system. Different compositions of bimetallic PdAg nanoparticles, Pd₈₀Ag₂₀, Pd₆₅Ag₃₅ and Pd₄₆Ag₅₄ can be obtained via adjusting the reaction parameters. For the formation process of the bimetallic PdAg nanoparticles, there have two-stage growth processes: firstly, nucleation a...

متن کامل

Fast, vacancy-free climb of prismatic dislocation loops in bcc metals

Vacancy-mediated climb models cannot account for the fast, direct coalescence of dislocation loops seen experimentally. An alternative mechanism, self climb, allows prismatic dislocation loops to move away from their glide surface via pipe diffusion around the loop perimeter, independent of any vacancy atmosphere. Despite the known importance of self climb, theoretical models require a typicall...

متن کامل

Synthesis, growth mechanism and thermal stability of copper nanoparticles encapsulated by multi-layer graphene

Copper nanoparticles encapsulated by multi-layer graphene have been produced in large quantity (in grams) by metal-organic chemical vapor deposition at 600 C with copper(II) acetylacetonate powders as precursor. The obtained graphene/copper shell/core nanoparticles were found to be formed by a novel coalescence mechanism that is quite different from the well-known dissolution–precipitation mech...

متن کامل

CO Oxidation at the Interface between Doped CeO2 and Supported Au Nanoclusters.

DFT+U calculations of CO oxidation by Au13 nanoclusters (NCs) supported on either CeO2 or doped (X-Ce)O2 (X = Au, Pt, Pd, Ti, Ru, Zr) show that doping the CeO2 support accelerates CO oxidation by the Mars-van Krevelen mechanism at the Au-(X-Ce)O2 interface. We find that Au, Pd, Pt, and Ti dopants significantly lower the vacancy formation energy of the CeO2 support and that electron donation fro...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Journal of the American Chemical Society

دوره 129 34  شماره 

صفحات  -

تاریخ انتشار 2007